Organic photovoltaic (OPV) cells, a third-generation solar cell technology that can convert solar energy into electricity, have been found to be more efficient than silicon cells under low light intensity indoor LED illumination.
These cells have also shown great potential for powering low consumption, off-the grid electronics in indoor environments.
Despite their huge potential, the power conversion efficiency of OPV cells is currently limited by substantial losses in their open-circuit voltage.
In addition, past studies suggest that when used for indoor illumination their absorption spectrum is far from optimal.
In a quest to overcome these limitations, a team of researchers at the Chinese Academy of Sciences in China and Linköping University in Sweden have recently designed a non-fullerene acceptor for that could enable high-performance organic photovoltaic cells for indoor applications.
This new acceptor, presented in a paper published in Nature Energy, can be blended with a polymer donor to obtain a photoactive layer with an absorption spectrum that matches that of indoor light sources.
The active layer that converts light energy into electric energy in organic solar cells, such as OPVs, is made up of a fine blend of two molecules, which are referred to as the donor and the acceptor.
These molecules can essentially be tuned to absorb types of light with different wavelengths.
“In this work, we present a donor/acceptor combination tuned to absorb visible light,” Jonas Bergqvist, one of the researchers who carried out the study.
“The donor and acceptor are tuned to also deliver a high voltage of 1.24V under solar illumination.”
Bergqvist and his colleagues combined the acceptor they developed, dubbed IO-4Cl, with a polymer donor known as PBDB-TF.
By combining these two molecules, they attained a photoactive layer with an absorption spectrum that is aligned with that of indoor light sources, which makes it ideal for indoor applications.
“Many high-performance acceptors for organic photovoltaics has had a low bandgap with absorption onset of ~800 nm,” Bergqvist said.
“In this work, we have modified the acceptor ITIC to increase the bandgap and this way match the material absorption with the indoor illumination spectrum (matching visible light 400-700 nm).”
The wide bandgap observed in the material devised by the researchers results in a higher voltage, enabling higher energy performance in indoor environments.
The researchers evaluated the performance of their acceptor in situations where the only illumination was a low-intensity LED light, simulating typical conditions in a variety of indoor spaces, including living rooms, libraries and shopping malls.
In these tests, the acceptor they developed enabled a power conversion efficiency of up to 26.1 percent, using a 1 cm2 device.
When Bergqvist and his colleagues tested larger (i.e. 4 cm2) devices powered by their acceptor, they achieved a remarkable power conversion efficiency of 23.9 percent.
“The digitalization of our society is ramping and Internet of Things and smart devices are a strongly growing market,” Bergqvist said..
“Many of these devices consume low amounts of power and efficient light energy harvesting devices can help powering them.
The high performance OPVs combined with printing and coating roll to roll production shows a great potential to power connected smart things.”
The wide-gap, non-fullerene acceptor developed by Bergqvist and his colleagues could finally enable higher performance in organic photovoltaic cells within indoor environments.
This could have important implications for the development of more advanced solar cell technology, which is not limited to outdoor applications.
“We can easily tune the absorption spectrum of these organic materials, so that we can maximize the efficiency for indoor light conversion,” Feng Gao, another researcher involved in the study, told TechXplore.
“This is not possible for commercial silicon solar cells. For this reason, I really believe that organic solar cells provide a unique and promising candidate for indoor applications such as powering the Internet of Things.”
In years to come, the new acceptor for OPV cells developed by this team of researchers could be used to create more energy-efficient devices.
In their future work, Bergqvist, Gao and their colleagues plan to continue developing the acceptor together with Jianhou Hou from the Chinese Academy of Science, investigating new ways to improve its performance.
For instance, increasing the photocurrent could lead to a further increase in power conversion efficiency. Calculations carried out by the researchers suggest that it theoretically could be possible to push its power conversion efficiency above 40 percent.
Herein we report a detailed study on the optoelectronic properties, photovoltaic performance, structural conformation, morphology variation, charge carrier mobility and recombination dynamics in bulk heterojunction (BHJ) solar cells comprising of a series of donor-acceptor (D-A) conjugated polymers as electron donors based on benzodithiophene (BDT) and 5,8-bis(5-bromothiophen-2-yl)-6,7-difluoro-2,3-bis(3-(octyloxy)phenyl)quinoxaline as a function of the BDT’s thienyl substitution (alkyl (WF3), alkylthio (WF3S) and fluoro (WF3F)).
It is manifested the synergistic positive effects of the fluorine substituents on the minimization of the bimolecular recombination losses, the reduction of the series resistances (RS), the increment of the shunt resistances (RSh), the suppression of the trap-assisted recombination losses, the balanced charge transport, the finer nanoscale morphology and the deeper highest occupied molecular orbital (EHOMO) versus the alkyl- and alkylthio- substituents.
According to these findings, WF3F:[6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) based-organic photovoltaic (OPV) device is a scarce example that feature a high power conversion efficiency (PCE) of 17.34% under 500 lx indoor LED light with a high open-circuit voltage (VOC) of 0.69 V, due to the suppression of the voltage losses and a PCE of 9.44% at 1-sun (100 mW/cm2) conditions, simultaneously.
More information: Yong Cui et al. Wide-gap non-fullerene acceptor enabling high-performance organic photovoltaic cells for indoor applications, Nature Energy (2019). DOI: 10.1038/s41560-019-0448-5
Journal information: Nature Energy